![]() I travel to horse shows and fairs setting up my display, and sometimes at local feed stores and events. I specialize in handpainted Jean Jackets, Custom-Orders,Sparkly shirts and an original and witty selection of printed designs on clothing ,etc. My sister Jean is a Painter/ Artist and my sister Katharine wrote the "Angelina Ballerina" Books.and this is what I've been doing. becoming " APT/Polly Produx" from1994-1999 and then went on my own with " Polly Paintbrush.". In the '80's I moved to Massachusetts and by 1990 "Polly Produx" began whole-heartedly setting up at Horse shows selling my "stuff." I was partners with my silk-screener Advanced Print Tech. This was as far as we could go back then.no Shatner Classes or World Championship Western Classes.but i know we could have won those too! We were undefeatable that year! What a team. It was in Denver in 1976 that I bought "Majestic Mountain Stonewall", a beautiful 2 year old Saddlebred gelding.and together he made all my childhood dreams come true! I trained and showed "Magic" and in 1980 we won the National Western Pleasure Grand Championship and went on to win both the International Western Pleasure Grand Championship,and the Sidesaddle Championship too. Then I moved to Denver and worked at The Capital Horseman Newspaper as Art Director/Advertising Manger, and then the Arabian Horse Journal. ![]() I had a job at Hallmark Cards waiting for me after graduation,so I lived in Kansas City and worked at Hallmark for a few years until the lure of the West (and my best friend) convinced me to move to Telluride Colorado, where I opened "Riding High Stable-The Un-Stable". We grew up riding Saddlebreds at Parkway Stables and in the Summers we rode horses wherever we could! My Senior year at Syracuse University School of Art I bought my first Saddlebred.no one could stop me then! My sisters and I had imaginary Horse Shows in our backyard growing up in Chicago.and we would whinny out the car window at horses whenever we saw one! Typical? Probably. It's what I do.Oh I can draw lots of things, I just draw horses best.
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![]() You’ll only notice clean pilot holes on the surface along with the perfect countersink hole for the screw to hide. These drill bits will provide you counterboring and countersinking in the same operation. All four pieces are designed for making holes with utmost precision. This countersink drill bit set is the choice you’d want to make when your job entails putting together quickly without having the level of the screw with the surface. BOSCH SP515 4 Piece Countersink Drill Bit Set Works on metallic surfaces along with wood and plasticģ.Industrial grade HSS steel made with black oxide finish.Its 1/4-inch round shank makes the bit a perfect option to be used for both handheld and stationary drills for amateurs and professionals alike. The 82° sharp pointed tips are sure to power through even metallic surfaces along with wood and plastic. Works well on both soft and hard surfaces alike, IRWIN is the perfect countersinking item you can wish for. Featuring a black oxide finish that resists rusting, this countersink drill bit set offers you better durability even if used daily. ![]() It also causes less vibration while drilling. The drill bit has a 5 flute design making it convenient to use ensuring a smoother operation. Each of the drill bits has its slot of storage. The design of the box is neat and made of sturdy material. ![]() This 5-piece countersink drill bit set comes in a neatly packaged box or a carrying case. Made of industrial-grade High-speed steel (HSS), it is the most durable item among all on our list. If you need a long-lasting drill bit that will serve your duties for many years then IRWIN could be a suitable option for you. IRWIN Countersink Drill Bit Set for Metal The titanium coating tends to wear off sooner than expectedĢ.Precise and sharp cutting will all tools.Carbon and high-speed steel made with titanium coating.Complete 23 piece package for professionals.And the final 23rd piece is the L-shaped wrench to tighten the screws. This creates a starting point for your drilling job so that the screw or the drill doesn’t move around. You’ll find a brass-made spring-loaded automatic center punch. ![]() We shouldn’t forget 2 more important tools that come with these 3 sets. They also come in handy for projects that require decorative plugs. Made from high-quality carbon steel with a 10mm round shank, these wood cutting bits are perfect for repairing damages and hiding screws. These 7 pieces range from 3 to 10 mm size in diameter.įinally, the 8 piece wood cutting drill set delivers the ultimate punch result. This is what you call an all-in-one countersink drill bit that can drill your surface for the screw and create a countersink as well. Then you have a 7 piece set of 3-pointed countersink drill bits. Their polished cutting edge made of high-speed steel is just too good for drilling any piece of extra thick wood. Each has a handle diameter of 1/4″ hex shank. All of these 23 pieces offer you drilling works that are more than perfect.įirst, it features a 6 piece set of 5-flute countersink drill bits. This amazing item features a total of 23 items, all from three different sets based on usage. If you’re a professional looking for a variety of drilling options, Rocaris Chamfer set could be the perfect thing for you. Rocaris Woodworking Chamfer Countersink Drill Bit Now let’s have a look at our top choices for the best drill bit items available on the market. Drill it deep enough to flush the screw head with the surface. When you’re done, drill the countersink hole with a bit same as the size of the screw’s head. You could use painter’s tape to mark the depth of the screw. Next drill a pilot hole corresponding to the size of the screw. This prevents the drill from wandering around on the wood surface. Mark the location where you want to make the hole and create a pilot hole with the pointed end of the screw or an awl. And the second is the countersink drilling.įirstly, measure the diameter of the countersink screw’s shaft and install a bit with the same diameter onto your drill. The first process involves drilling normally as you’d do for any screw.
In addition, hydrogen has at least one “active” lone pair. Conversely, these atoms have a high negative charge. Hydrogen attaches to highly electronegative atoms and acquires a high positive charge. They form due to the unequal charge distribution in the molecule. It would help if you remembered that hydrogen bonds do not form spontaneously. Therefore, hydrogen bonds are an essential aspect of chemical bonding. The greater the hydrogen-atom-atom ratio, the stronger the hydrogen bonds will be. As you go down the group, the boiling point of the compound increases. The PH3 molecule has a low boiling point, and the hydrogen atom is attached to one of the electronegative atoms. Instead, the London dispersion forces occur between the nh3 molecules. NH3 can form hydrogen bonds with water, but PH3 cannot. The molecule does not have a trigonal planar geometry and a dipole moment of 0.58D. PH3 is a polar molecule with a lone pair on one atom. However, ch3nh2 or ch3oh can form hydrogen bonds between molecules of the same type. Moreover, phosphorus cannot be used as a proton acceptor, as nh3 is a nearly universal proton acceptor. ![]() In addition, the phosphorous atom’s electrons are located in the third orbital, far from the nucleus. This is because it cannot render the opposite charge on the hydrogen-bonded. The phosphorus atom is a poor candidate for hydrogen bonding. These interactions are responsible for deviations from the ideal gas law. The electrostatic forces fall off with increasing distance between two molecules, and these interactions become essential at high pressures. These interactions are a sum of both repulsive and attractive forces. These interactions occur when positive or negatively charged species interact with one another. Hydrogen-hydrogen bonds are also a result of electrostatic interactions between two molecules. Hydrogen bonds also play a vital role in a molecule’s nucleotide bases. The two molecules then form a dipole-dipole intermolecular force, which requires considerable energy to break. The partially positive end of the hydrogen atom is attracted to the partially negative end of the oxygen atom. Hydrogen bonds occur when the hydrogen atom is bonded to oxygen, nitrogen, or fluorine. Moreover, the PH3 dipole-dipole interactions also have a pronounced effect on the boiling and melting points of the substance. ![]() However, because hydrogen bonds are more robust than dipole-dipole interactions, they can be used to separate polar molecules in solution. These interactions are weaker than the dipole-dipole interactions of most other molecules, including water. Hydrogen-hydrogen interactions only happen between organic molecules, forming hydrogen bonds between them. The phosphine molecules have a dipole moment of 0.58D, much smaller than the NH3 dipole moment. These forces are more potent than the Van der Waals forces. The molecules of the interhalogen compound PH3 form a dipole-dipole interaction and a hydrogen bond. A molecule with a similar structure to a PH3 molecule is a tetrahedral molecule. A polar molecule, such as carbon dioxide, is a tetrahedral molecule. The lone pair on the central O contributes to its polarity. However, its planar shape makes it nonplanar. Therefore, a molecule is polar if its electronegativity is less than 0.4.īecause of the P-H bond, PH3 is a polar atom. ![]() The two types of molecules share electrons symmetrically. Nonpolar molecules contain one type of atom, while symmetrical molecules contain two or more atoms. The electronegativity of a molecule varies widely, and the lone pairs on outer atoms are considered nonpolar. Hence, the polar molecule is a water molecule. Therefore the lone pair pushes down when compared to the lone pair. Unlike hydrogen, which only needs two valence electrons to form a fuller outer shell, phosphorous has a dipole moment that is less than one D. ![]() Though $P$.PH3 has a Lewis structure that contains eight valence electrons. Hint: The size of the P atom is greater than the N atom, down the group basicity of the atom decreases when the size of the atom increases and the electron density decreases. ![]() The next business day, March 20, 2023, RJR got a court order allowing Vuse Solo menthol to stay on the market while it appeals FDA’s order. Reynolds Vapor Company’s Vuse Vibe menthol e-cigarette product.” FDA had denied Vuse Vibe menthol the day before, on January 24, 2023. According to the FDA’s Malist of marketing denial orders, “On January 25, 2023, the United States Court of Appeals for the Fifth Circuit granted a temporary administrative stay of the MDO issued to R.J. RJR is not simply accepting these marketing denials. In particular, FDA still has not acted on any flavors of Vuse Alto e-cigarettes, the most popular of the Vuse product line with kids. As it almost did under President Trump, FDA should protect public health now by applying its enforcement discretion to take all menthol (and remaining flavored) e-cigarettes off the market unless or until FDA made a positive decision on their pending applications to allow their marketing. Since this argument applies broadly and it also likely to apply to all menthol e-cigarettes, especially since overall e-cigarettes as consumer products do not help adults stop smoking cigarettes. This is the same logic that FDA used to deny marketing orders for the other menthol e-cigarettes. NYTS data also found Vuse to be the second most common brand youth e-cigarette users reported “usually” using. Given these existing differences in youth risk, applicants need to provide robust evidence to demonstrate that using their menthol-flavored e-cigarette products are likely to promote complete switching or are likely to significantly reduce combustible cigarette use in adult smokers beyond that facilitated by tobacco-flavored e-cigarettes. In contrast, data indicate tobacco-flavored e-cigarettes do not have the same appeal to youth and therefore do not pose the same degree of risk. While FDA does not make its detailed analysis public for marketing denial orders, it summarized its thinking in the press release:Įxisting evidence, including data from the 2022 National Youth Tobacco Survey (NYTS), shows that non-tobacco-flavored e-cigarettes, including menthol-flavored e-cigarettes, have a known and substantial risk with regard to youth appeal, uptake and use. This action follows FDA denials for RJR Vuse Ciro menthol and JTI Logic menthol e-cigarettes. FDA has continued to deny marketing authorization for menthol e-cigarettes with its Maannouncement that it had denied marketing authorization for two RJR Vuse Solo menthol cartridges. ![]() Moreover, Frontline is a massive first-person PVP shooter with “epic 100+ player battles.” ![]() A deep class system and an extensive array of tactical gadgets/tools enable deep customization and satisfying gameplay – outsmarting enemy teams is the key to victory. Tom Clancy’s Ghost Recon Frontline is the latest free-to-play team-based shooter to join Ubisoft’s ever-expanding catalog. ![]() Today, the next Ghost Recon chapter was announced. New game modes, characters, tactical tools, maps, and more will be added each season.Earlier this year, Ubisoft unveiled Tom Clancy’s XDefiant – “fast-paced firefights meets punk rock mosh pits.” XDefiant bridged the gap between most of Tom Clancy’s beloved game franchises by showcasing playable operators from Splinter Cell, The Division, and more. Tom Clancy’s Ghost Recon Frontline promises an ever-evolving world. Time goes on, but the conflict never ends. ![]() Use different abilities, call down tactical supplies, switch between units, adapt and showcase exceptional teamwork while competing with others. Featuring 100+ players in teams of three, the flagship Expedition mode is the ultimate test of teamwork: it includes dynamic objectives strewn across the massive open map with no converging circle, where players must work together and utilize their combined skills in order to call for extraction. The game offers various game modes, from quick and casual to highly tactical. The game features an immersive, full first-person perspective, while staying true to its fundamental values of teamwork, strategic gameplay, and high military authenticity. Tom Clancy’s Ghost Recon Frontline is a brand-new take on the franchise, and the first in the series to introduce massive PvP experience with full cross-platform support. Explore multiple landmarks and distinct biomes with ever-changing weather conditions, from high mountains and dense forests to ruthless arid lands. Previously a beautiful and peaceful country, it is now overrun by a corrupt mining corporation, which leads to forcible displacement of local communities and massive environment pollution. MASSIVE BATTLEGROUNDĭiscover Drakemoor Island, an open world full of diverse environments. Socialize with your friends and build powerful synergies through different compositions of contractors and their complementary abilities. Progress through the game via an advanced unit system, upgrade and customize each contractor to fit your strategy, and even choose different skill paths to unlock within each class. Team up with players from all around the world, across platforms through an impactful and diverse class system where each class is highly specialized, filling in distinct tactical roles. Think outside the box, combine skills, adapt, and outsmart enemies your way. The battlefield is yours to control as these unique features encourage strategic choice and empower players to try different approaches. Tom Clancy’s Ghost Recon Frontline is a tactical-action game where split-second decisions are essential. Adapt to an evolving battlefield by calling on tactical reinforcements, such as deadly auto turrets, smoke screen drones, and massive barricades. Here are the game’s key features: Tom Clancy’s Ghost Recon Frontline Key Features UNBOUND TACTICAL FREEDOMīecause there are multiple ways to win each match, it is entirely up to you what kind of strategic approach you take. ![]() "The machines couldn't get over the beds. The past three weeks of rain have complicated open-field lettuce harvesting at Lucassen Agri Cultuur in the Netherlands. Lucassen Agri Cultuur adds iceberg lettuce to its range "Machine harvesting is a must for us" So far, 75 per cent of the produce has already been harvested and placed on the market, but the current campaign seems to have more lows than highs. ![]() ![]() There are approximately 350 hectares invested in melons and watermelons this year by the producers' organization O.P Agricola Campidanese. In an era that decries food waste and heavy chemical spraying, the European Union's intractable stance on the cosmetic disease citrus black spot (CBS) is an indefensible piece of politicking which the South African citrus industry will no longer accept.Even more so when it is financially crippling a…Ībnormal weather is the main cause Italian melons and watermelons still teetering “We had a late start to the cherry season, but the heat in June brought the crop forward leading to a condensed season,” said Douw Kruger,…Ĭitrus Growers' Association says recent interceptions from non-CBS areas demonstrate fallibility of tests South African citrus wants World Trade Organisation to decide on EU citrus black spot measure The cherry harvest at Haygrove, based in Hereford, England started in June, it was around two weeks later than a ‘normal’ year due to an unseasonably cold Spring. "There's always massive demand, but more and more growers,…ĭouw Kruger - Haygrove “Volumes are good, we will pick around 650 tonnes of cherries this season" But harvesting starts on Monday at one of the few remaining Belgian growers, Ronald Vanderkelen. The dismal spring and cold first weeks of August mean it is slightly later than in other years. The new Belgian grape season is about to begin. Grape grower, Ronald Vanderkelen: "Belgian grape demand rises annually, but energy prices stay far too high" We endured some challenging weather during the spring time in Poland. Lower volumes for Jonaprince and Idared in upcoming Polish apple seasonĭespite challenging weather in Poland, the new apple harvest is looking positive according to Dominik Woźniak, of Polish apple exporter Rajpol: “The 2023 harvest of the Rajpol Cooperative is looking promising. ![]() The digital audio converter can be used as MP3 converter, WMA converter, M4A converter, and so on. 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![]() Call today at 21 or come by the shop at 7210 Polar Bear, San Antonio, TX, 78238. Rubens is one of the best shops I have ever been to and its a shame I dont live closer. Perform maintenance, preventive maintenance and repair of a. Get Your Cars AC Compressor Repaired Rubens Auto Repair in San Antonio 21. Places Near Cleburne, TX with Auto Ac Repair. Must have a valid Texas drivers license and good driving record required. Just heads up trying to cut cost at Sam & Joes may cost you more. From Business: We are a family owned and operated shop offering complete automotive repair by certified technicians. After that entire experience with Sam & Joes all I asked of Josh was to replace the tire. There wasn’t anything wrong with my struts prior Sam & Joes correcting the bolt that was too long and my tires maybe had 250 miles on them. The next time you’re researching small electric motor repair shops, we hope you’ll check out Gatewood Electric. It appears he doesn’t plan on doing right by me. Whether your electric motor is running a 1,500-horsepower water pump or a fan motor for an AC unit, we can find exactly. Should you be in need of fleet services, preventative maintenance, or standard auto repairs like auto air conditioning repair in Keene, TX, we’re the place to call. Welcome to Main Street Elite Automotive Repair We are your one-stop shop for all services having to do with automotive repair. A/C FREON HOW DOES A CAR A/C WORK Locations in Cleburne, TX Find Cleburne, TX Car A/C Repair Near You We'll help keep your ride cool. Josh (owner) hasn’t rectified the issue as of yet 07/18/22. Proudly Serving Cleburne and Surrounding Areas. I had the tire replaced the day of our conversation sent Josh the invoice per request and followed up with a call to verify that the invoice was received. ![]() He basically said he wasn’t responsible for the overspray but if I send him the invoice for the purchase of my tire he will reimburse me. The day of Josh reaching out I explained everything again. I expressed my experience in the form of a curtesy note left on the desk of the owner Josh on the day of pickup 06/30/22. We are the Cleburne air conditioning repair service experts for all makes and models of air conditioners in Cleburne. I asked Mike if I could get a wash, his response was their not a car wash ?. Mike said the bolt used in the repair was too long and it has been corrected.īut now the car is leaning the passenger side air struts are now bad which will be an additional $2,438.58.ĭuring this process of driving my car from the rear of their business to front parking area, my fender weld was damaged cutting a groove around my passenger front tire and my car accumulated paint overspray from the paint and body shop next door. A few weeks later I had to return due to a squeaking noise coming from the rear wheel area. read more Mike Mebane (big Mike) quoted me $2,303.39 to replace a brake actuater on an 08 S550. Mike Mebane (big Mike) quoted me $2,303.39 to replace a brake actuater. "You know, " he said, "not everyone is as lucky as us … and Liz does a good deal for people, as much as anybody I ever met. Bloomberg took the microphone again to thank several people and Ms. It’s just great, the mayor is so wonderful to work with and if there were more men like him in America, we wouldn’t be in the dilemma we’re in right now!" The surging crowd exploded, applauding, and Mr. But anyway, that’s the serious part of this. I have a feeling we need one right here in Manhattan. But I think we’d all be very proud if you could visit one of the anti-violence centers in Queens and the Bronx-I mean in Brooklyn, we’re gonna build one in the Bronx, we’re gonna build a lot of them. "Ladies and gentlemen, we’re all here, we’re eating and drinking, we’re rubbing elbows, we’re exchanging cards. Mister Softee, which is most popular in the Northeast but operates about 600 trucks across 16 states, was founded in 1956 by two Philadelphia brothers, William and James Conway. Mister Softee’s has been successful in finding a very special place in our hearts, and in our City, as they offer their own premium brand served up in cones, cups and milkshakes. The familiar jingle of the ice cream man is one we associate with warm summer days, childhood, and a perfectly swirled ice cream cone. Smith as "one of the most wonderful women ever met" and she took the podium to speak: More recent years we have sidewalk vendors and various attempts at different ice cream ‘trucks’ selling store bought items. ![]() I’m sure you’ll all be there, but tonight I want to say thank you to you for supporting the Mayor’s Fund, so thanks, New York!" He then introduced Ms. We have the Mets … the Yankees final game at Yankees Stadium on Sunday night. Open a couple of weeks ago, tonight’s Swifty’s. There is no better treat for your guests, coworkers, attendees or. Mister Softee trucks are available for company picnics, fairs, and birthday parties. ![]() We are compliant with all local and state agency regulations & requirements. ![]() "Ladies and gentlemen, I want to welcome all of you to my favorite annual fund-raiser in a tent on 73rd Street! We had the U.S. Complete Soft Serve Ice Cream Stand on Wheels. Smith on the small central stage inside the tent. Around 7:30 the lights in the tent dimmed momentarily and Mayor Bloomberg appeared with Ms. |
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